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Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-iodophenyl)-
Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-iodophenyl)-
CAS:144970-30-9 M.F.:C34H28I4 M.W.:944.204018592834
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Product Name:1,​3,​5,​7-​Tetrakis(4-​iodophenyl)​adamantane
Synonymous:TIPA;1,​3,​5,​7-​Tetrakis(4-​iodophenyl)​tricyclo[3.3.1.13,​7]​decan ; 1,​3,​5,​7-​Tetrakis(p-​iodophenyl)​adamantane
CAS:144970-30-9
Basic Info
M.F. C34H28I4 M.W. 944.20212
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It can be used as an intermediate to synthesize MOF ligands or COF monomers:PAFad [r5]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Mathias, Lon J.; Reichert, Veronica R.; Muir, Andrew V. G.; Chem. Mater. 1993, 5(1), 4-5, DOI: 10.1021/cm00025a002 ; Synthesis of rigid tetrahedral tetrafunctional molecules from 1,​3,​5,​7-​tetrakis(4-​iodophenyl)​adamantane
2) Lu, Weigang; Yuan, Daqiang; Zhao, Dan; Schilling, Christine Inge; Plietzsch, Oliver; Muller, Thierry; Brase, Stefan; Guenther, Johannes; Blumel, Janet; Krishna, Rajamani; Li, Zhen; Zhou, Hong-Cai; Chem. Mater. 2010, 22(21), 5964-5972, DOI: 10.1021/cm1021068 ; Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage​/Separation
3) Wang, Shujun; Oldham, Warren J., Jr.; Hudack, Raymond A., Jr.; Bazan, Guillermo C.; Journal of the American Chemical Society 2000, 122(24), 5695-5709, DOI: 10.1021/ja992924w ; Synthesis, Morphology, and Optical Properties of Tetrahedral Oligo(phenylenevinylene) Materials
4) Xie, Lin-Hua; Suh, Myunghyun Paik; Chem. Eur. J. 2013, 19(35), 11590-11597, DOI: 10.1002/chem.201301822 ; High CO2-​Capture Ability of a Porous Organic Polymer Bifunctionalized with Carboxy and Triazole Groups
5) Verde-Sesto, Ester; Merino, Estibaliz; Rangel-Rangel, Elizabeth; Corma, Avelino; Iglesias, Marta; Sanchez, Felix; ACS Sustainable Chem. & Eng. 2016, 4(3), 1078-1084, DOI: 10.1021/acssuschemeng.5b01147 ; Postfunctionalized Porous Polymeric Aromatic Frameworks with an Organocatalyst and a Transition Metal Catalyst for Tandem Condensation-​Hydrogenation Reactions
Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-iodophenyl)-
Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-iodophenyl)-

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