SH-UIO-66
SH-UIO-66
CAS:1435475-69-6
M.F.:
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Product: UIO-66-(SH)2
Synonyms: Zr-DMBD
CAS：1435475-69-6
Basic Information
| Unit MF. | C48H24O32S12Zr6 | Unit MW. | 2044.81 | ||
| Coordination Metal | Zr | Linkers | 2,5-dimercaptoterephthalic acid （CAS：25906-66-5） | ||
| Pore Size | 0.7nm; 1.0nm | Pore volume | 0.4 cm3/g | ||
| Surface Area | BET Specific surface 700 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Yellow Powder |  |
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| Particle Size | 50-100nm nanoparticles | |||
Stability
1) UIO-66-(OH)2 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 350 ° C
2）High thermal stability, thermal decomposition temperature above 350 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 120 degree in vacuum.
2) It is recommended to activate for 12 hours at 120 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) UIO-66-(OH)2, with branch mercapto groups, could be further derivated with enzyme or peptide in biochemical research
2) UIO-66-(OH)2, with branch mercapto groups, could be further derivated with enzyme or peptide in biochemical research
Characterizations
References
1) Yee, Ka-Kit; Reimer, Nele; Liu, Jie; Cheng, Sum-Yin; Yiu, Shek-Man; Weber, Jens; Stock, Norbert; Xu, Zhengtao; J. Am. Chem. Soc. 2013, 135(21), 7795-7798, DOI: 10.1021/ja400212k ; Effective Mercury Sorption by Thiol-Laced Metal-Organic Frameworks: in Strong Acid and the Vapor Phase