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TSCOF-1
TSCOF-1
CAS:1426152-92-2 M.F.:(C21H18N6.C14H4O6)X M.W.:622.59
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ProductTSCOF-1
Synonyms2D-NTCDA-TTTA COF ; NTCDA-TAPT COF
CAS:1426152-92-2
Basic Information
Unit MF. (C21H18N6.C14H4O6)x Unit MW.  
Linkers

1) 1,4,5,8-naphthalene tetracarboxylic anhydride (CAS: 81-30-1 );

2) 1,4-benzenediamine (CAS:106-50-3)

Pore Size 4nm (1-1.3nm) Pore volume 0.3cm3/g
Surface Area BET Specific surface 700-1000 m2/g 
Analog Structure  
Product Property
Appearance

 Brown Solid

 
Particle Size  irregular clusters
Stability
1) Stable in aqueous solution, stable in acidic and alkaline conditions
2) Good thermal stablility, thermal decomposition temperature above 400℃
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
Other Features
Fluorescence: NA
Applications
1) For gas and pollutant adsorption
2) Rigid pores to load other catalysts
Characterizations
XRD
SEM
SEM-TSCOF-1
BET
BET-TSCOF-1
FTIR
NA
References
 
1) Liebl, Mario R.; Senker, Juergen; Chemistry of Materials 2013, 25(6), 970-980, DOI:  10.1021/cm4000894 ; Microporous Functionalized Triazine-Based Polyimides with High CO2 Capture Capacity
2) Patent:CN110218317A   Preparation method of polyimide covalent organic framework for energy storage device electrode
3) Patent:CN114773556A   Green solid phase synthesis method covalent organic framework material
4) Liu, Yannan ; Lu, Yiyue; Hossain Khan, Arafat; Wang, Gang ; Wang, Yong; Morag, Ahiud; Wang, Zhiyong; Chen, Guangbo; Huang, Shengyun; Chandrasekhar, Naisa; Sabaghi, Davood; Li, Dongqi; Zhang, Panpan; Ma, Dongling ; Brunner, Eike; Yu, Minghao; Feng, Xinliang; Angew.  Chem., Int. Ed. 2023, 62(30), e202306091, DOI: 10.1002/anie.202306091; Redox-Bipolar Polyimide Two-Dimensional Covalent Organic Framework Cathodes for Durable Aluminium Batteries 
XRD TSCOF-1-CS018206.pdf Download
TSCOF-1
TSCOF-1

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