Product: TpPa-COF-(CH3)2
Synonyms: 1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 2,5-dimethyl-1,4-benzenediamine
CAS: 1414350-38-1
Basic Information
Unit MF. |
C9H6O6.C8H12N2 |
Unit MW. |
346.33462 |
Coordination Metal |
None |
Linkers |
1,3,5-triformylphloroglucinol (Tp) 2,5-dimethylbenzene-1,4-diamine (Pa-(CH3)2)
|
Pore Size |
~1.27 nm |
Pore Volume |
0.68 cm³/g |
Surface Area |
124.3 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
Red Powders |
|
Particle Size |
Irregular bulk particles |
Stability
1) Stable in water and ethanol
2) Thermal decomposition temperature > 300°C
Preservation
1) Store in a dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use
Other Features
Fluorescence: NA
Applications
1) Photocatalytic hydrogen production
2) Gas adsorption and separation
Characterizations
References
1) Jin Zhang, Cheng Cheng, Lijiang Guan, Hai-Long Jiang, Shangbin Jin; J. Am. Chem. Soc. 2023, 145, 21974−21982, DOI: 10.1021/jacs.3c06764; Rapid Synthesis of Covalent Organic Frameworks with a Controlled Morphology: An Emulsion Polymerization Approach via the Phase Transfer Catalysis Mechanism