PCN-222(Mn)
PCN-222(Mn)
CAS:1403461-01-7
M.F.:
M.W.:
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Product: PCN-222(Mn)
Synonyms: MOF-545(Mn)
CAS：1403461-01-7
Basic Information
| Unit MF. | C96H52N8O32Zr6 | Unit MW. | 2376.81848 | ||
| Coordination Metal | Zr | Linkers | H2TCPP (CAS: 14609-54-2) | ||
| Pore Size | 3.7nm; 1.3 nm | Pore volume | 1.5 cm3/g | ||
| Surface Area | BET Specific surface 2000 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Dark Purple Powder |  |
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| Particle Size | 2um*50nm needle particles; 200nm*20nm nanoparticles | |||
Stability
1) PCN-222 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
Other Features
Fluorescence: λex=413nm, λem=643nm
Applications
1) PCN-222 has rigid channel framework, which is good carrier of catalyst and poentail material for gas and pollutant adorption.
2) With a pore size up to 3.7nm, PCN-222 is a pontential material for adsorption of drug molecular and enzyme/peptide
3) PCN-222(Mn) is able to convert O2 to singlet oxygen under light condition. It could be used as photocatalyst in organic reaction or as biosensors.
Characterizations
References
1) D. Feng, Z.-Y. Gu, J.-R. Li, H.-L. Jiang, Z. Wei, and H.-C. Zhou, Angew. Chem. 2012, 124, 10453-10456, DOI: 10.1002/ange.201204475 ; Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
2) W. Morris, B. Volosskiy, S. Demir, F. Gándara, P. L. McGrier, H. Furukawa, D. Cascio, J. F. Stoddart, O. M. Yaghi, Inorg. Chem. 2012, 51, 6443-6445, DOI: 10.1021/ic300825s ; Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
3) Meie He, Yanan Chen, Cheng Tao, Qingqing Tian, Lu An, Jiaomin Lin, Qiwei Tian, Hong Yang, and Shiping Yang, ACS Appl. Mater. Interfaces 2019, 11(45), 41946–41956, DOI: 10.1021/acsami.9b15083 ; Mn–Porphyrin-Based Metal–Organic Framework with High Longitudinal Relaxivity for Magnetic Resonance Imaging Guidance and Oxygen Self-Supplementing Photodynamic Therapy