Bis(N,N'-dimethylpiperazine)tetra[copper(I) iodide]
Bis(N,N'-dimethylpiperazine)tetra[copper(I) iodide]
CAS:1401708-91-5
M.F.:C12H28Cu4I4N4
M.W.:990.18
Pricing
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Product: (CuI)4(N,N′-Dimethylpiperazine)2
Synonyms: Bis(1,4-dimethylpiperazine-κN1)tetra-μ3-iodotetracopper
CAS：1401708-91-5
Basic Information
| Unit MF. | C12H28Cu4I4N4 | Unit MW. | 990.18 | ||
| Coordination Metal | Cu | Linkers |
N,N′-Dimethylpiperazine (CAS: 142-29-0) |
||
| Pore Size | NA | Pore Volume | NA | ||
| Surface Area | NA | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | NA | |||
| Particle Size | NA | |||
Stability
1) Thermal decomposition temperature: 145–180°C (TGA analysis).
Preservation
1) Keep in dry and cool conditions.
Other Features
1) Photoluminescence: Exhibits photoluminescence at 77 K with an emission wavelength of approximately 558 nm (orange) and an excitation wavelength of approximately 334 nm.
2) Mechanism: Cluster-centered (3CC) transitions involving halide-to-metal charge transfer (3XMCT) and metal-centered transitions (3MC).
2) Mechanism: Cluster-centered (3CC) transitions involving halide-to-metal charge transfer (3XMCT) and metal-centered transitions (3MC).
Applications
1) Gas sensing: Can be used as a gas sensor for detecting amine vapors.
2) Photoluminescent material: Suitable for low-temperature photoluminescence applications.
3) Chemical detection: Can detect and identify specific organic amine gases.
2) Photoluminescent material: Suitable for low-temperature photoluminescence applications.
3) Chemical detection: Can detect and identify specific organic amine gases.
Characterizations
References
1) Jason P. Safko, Jacob E. Kuperstock, Shannon M. McCullough, Andrew M. Noviello, Xiaobo Li, James P. Killarney, Caitlin Murphy, Howard H. Patterson, Craig A. Bayse, Robert D. Pike; Dalton Transactions (2012), 41, 11663-11674, DOI: 10.1039/c2dt31241g; Network formation and photoluminescence in copper(I) halide complexes with substituted piperazine ligands.