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[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
CAS:1394899-62-7 M.F.:C24H22O4 M.W.:374.42908
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Product Name:[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
Synonymous:TPDC-4CH3 ; H2TTTP;2',​3',​5',​6'-​Tetramethyl[1,​1':4',​1''-​terphenyl]​-​4,​4''-​dicarboxylic acid
CAS:1394899-62-7
Basic Info
M.F. C24H22O4 M.W. 374.42908
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:UIO-68-4Me / PCN-57 (Zr, Hf) [r1,r3] ; PCN-72 [r2];
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) Jiang, Hai-Long; Feng, Dawei; Liu, Tian-Fu; Li, Jian-Rong; Zhou, Hong-Cai; J. Am. Chem. Soc. 2012, 134(36), 14690-14693, DOI: 10.1021/ja3063919 ; Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal-​Organic Frameworks
2) Liu, Yangyang; Chen, Ying-Pin; Liu, Tian-Fu; Yakovenko, Andrey A.; Raiff, Aaron M.; Zhou, Hong-Cai; CrystEngComm 2013, 15(45), 9688-9693, CrystEngComm, 2013,15, 9688-9693, Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains
3) Klet, Rachel C.; Liu, Yangyang; Wang, Timothy C.; Hupp, Joseph T.; Farha, Omar K.; J. Mater. Chem. C 2016, 4(4), 1479-1485, DOI: 10.1039/C5TA07687K ; Evaluation of Bronsted acidity and proton topology in Zr- and Hf-​based metal-​organic frameworks using potentiometric acid-​base titration
4) Pang, Jiandong; Yuan, Shuai; Qin, Junsheng; Wu, Mingyan; Lollar, Christina T.; Li, Jialuo; Huang, Ning; Li, Bao; Zhang, Peng; Zhou, Hong-Cai; J. Am. Chem. Soc. 2018, 140(39), 12328-12332, DOI: 10.1021/jacs.8b07411 ; Enhancing Pore-​Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal-​Organic Frameworks

5) Dascalu, Ioan-Andrei; Shova, Sergiu; Dumitrescu, Dan Gheorghe; Roman, Gheorghe; Bratanovici, Bogdan-Ionel; Ardeleanu, Rodinel; Lozan, Vasile; Polyhedron 2019, 170, 463-470, DOI: 10.1016/j.poly.2019.05.066 ; Coordination polymers of Cu(II)​, Co(II) and Cd(II) based on a tetramethyl-​substituted terphenyldicarboxylic acid

1394899-62-7-CS017249.pdf Download
1394899-62-7-CS017249-MS.pdf Download
[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-

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