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(biphenyl-3, 3′,5, 5′-tetra-(phenyl-4-carboxylic acid))
(biphenyl-3, 3′,5, 5′-tetra-(phenyl-4-carboxylic acid))
CAS:1383925-31-2 M.F.:C40H26O8 M.W.:634.62964
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Product Name:(biphenyl-3, 3′,5, 5′-tetra-(phenyl-4-carboxylic acid))
Synonymous:H4TCBP
CAS:1383925-31-2
Basic Info
M.F.  C40H26O8 M.W.  634.62964
Appearance  
Properties
1)  1383925-31-2 is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF materials: NOTT-202 [r1]; ZJU-30 [r2]; HOF-​TCBP [r3]; NU-1010 [r4]; UMCM-​312/UMCM-​313 [r5]
2) It was used as monomer for HOF material: HOF-​TCBP [r3]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Yang, S.; Lin, X.; Lewis, W.; Suyetin, M.; Bichoutskaia, E.; Parker, J.; Tang, C.; Allan, D.; Rizkallah, P.; Hubberstey, P.; Champness, N.; Thomas, K.; Blake, A.; Schröder, M.   Nat. Mater. 2012,  11, 710–716, DOI: 10.1038/nmat3343 ; A partially interpenetrated metal–organic framework for selective hysteretic sorption of carbon dioxide 
2) Cai, J.; Yu, J.; Xu, H.; He, Y.; Duan, X.; Cui, Y.; Wu, C.; Chen, B.; Qian, G. Cryst. Growth Des. 2013, 13, 5, 2094-2097, DOI: 10.1021/cg400164m ; A Doubly Interpenetrated Metal–Organic Framework with Open Metal Sites and Suitable Pore Sizes for Highly Selective Separation of Small Hydrocarbons at Room Temperature 
3) Hu, F.; Liu, C.; Wu, M.; Pang, J.; Jiang, F.; Yuan, D.; Hong, M. Angew. Chem., Int. Ed. 2017, 56(8), 2101-2104, DOI:10.1002/anie.201610901 ; An Ultrastable and Easily Regenerated Hydrogen‐Bonded Organic Molecular Framework with Permanent Porosity
4) Kato, S.; Otake, K.-i.; Chen, H.; Akpinar, I.; Buru, C. T.; Islamoglu, T.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2019, 141, 2568– 2576, DOI: 10.1021/jacs.8b12525 ; Zirconium-Based Metal–Organic Frameworks for the Removal of Protein-Bound Uremic Toxin from Human Serum Albumin
5) Ma, J.; Tran, L.; Matzger, A.; Cryst. Growth Des. 2016, 16(7), 4148-4153, DOI:10.1021/acs.cgd.6b00698 ; Toward Topology Prediction in Zr-Based Microporous Coordination Polymers: The Role of Linker Geometry and Flexibility
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(biphenyl-3, 3′,5, 5′-tetra-(phenyl-4-carboxylic acid))
(biphenyl-3, 3′,5, 5′-tetra-(phenyl-4-carboxylic acid))

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