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2,5-Dichloroterephthalic acid
2,5-Dichloroterephthalic acid
CAS:13799-90-1 M.F.:C8H4O4Cl2 M.W.:235.02096
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Product Name:2,5-Dichloroterephthalic acid
Synonymous:BDC-Cl2
CAS:13799-90-1
Basic Info
M.F.  C8H4O4Cl2 M.W.  235.02096
Appearance  
Properties
1)  13799-90-1 is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis: MOF-5-Cl2 [r1]; [Zn2(bdc-​Cl2)​2(dabco)​]​ [r4] ; UIO-66-Cl2 [r5]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Deng, Hexiang; Doonan, Christian J.; Furukawa, Hiroyasu; Ferreira, Ricardo B.; Towne, John; Knobler, Carolyn B.; Wang, Bo; Yaghi, Omar M.; Science 2010, 327(5967), 846-850, DOI: 10.1126/science.1181761 ; Multiple Functional Groups of Varying Ratios in Metal-​Organic Frameworks
2) Uemura, Takashi; Ono, Yukari; Hijikata, Yuh; Kitagawa, Susumu; J. Am. Chem. Soc. 2010, 132(13), 4917-4924, DOI: 10.1021/ja100406k ;  Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization
3) Xue, Ming; Zhang, Zhangjing; Xiang, Shengchang; Jin, Zhao; Liang, Chengdu; Zhu, Guang-Shan; Qiu, Shi-Lun; Chen, Banglin; J. Mater. Chem. 2010, 20(19), 3984-3988, DOI: 10.1039/b927486c ;  Selective gas adsorption within a five-​connected porous metal-​organic framework
4) Uemura, Kazuhiro; Yamasaki, Yukari; Onishi, Fumiaki; Kita, Hidetoshi; Ebihara, Masahiro; Inorg. Chem. 2010, 49(21), 10133-10143, DOI: 10.1021/ic101517t ; Two-​Step Adsorption on Jungle-​Gym-​Type Porous Coordination Polymers: Dependence on Hydrogen-​Bonding Capability of Adsorbates, Ligand-​Substituent Effect, and Temperature
5) Biswas, Shyam; Van Der Voort, Pascal; Eur. J. Inorg. Chem. 2013, 2013(12), 2154-2160, DOI: 10.1002/ejic.201201228 ; A General Strategy for the Synthesis of Functionalised UiO-​66 Frameworks: Characterisation, Stability and CO2 Adsorption Properties
HNMR-13799-90-1-CS013184.pdf Download
13799-90-1-CS014140.pdf Download
2,5-Dichloroterephthalic acid
2,5-Dichloroterephthalic acid

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