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Pyridinium, 1,1′,1′′-[1,3,5-benzenetriyltris(methylene)]tris[4-cyano-, bromide (1:3), homopolymer
Pyridinium, 1,1′,1′′-[1,3,5-benzenetriyltris(methylene)]tris[4-cyano-, bromide (1:3), homopolymer
CAS:1374677-13-0
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Product: CTF-TPMs
Synonyms: Pyridinium, 1,1′,1′′-[1,3,5-benzenetriyltris(methylene)]tris[4-cyano-, bromide (1:3), homopolymer
CAS: 1374677-13-0
Basic Information
| Unit MF. | Unit MW. | ||||
| Coordination Metal | None | Linkers |
1,3,5-Tris(4-cyanopyridinium-1-ylmethyl)benzene tribromide (TPM) |
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| Pore Size | 1.5–6 nm | Pore Volume | 0.11–0.15 cm3/g | ||
| Surface Area | 715–1206 m2/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Black Solid | |||
| Particle Size | Uniform Spherical Structure | |||
Stability
1) CTF-TPMs remain structurally intact after soaking in strong acid (6M HCl) and strong base (6M NaOH) solutions for 24 hours.
2) Thermogravimetric analysis shows that CTF-TPMs maintain a complete framework structure up to 540°C.
2) Thermogravimetric analysis shows that CTF-TPMs maintain a complete framework structure up to 540°C.
Preservation
1) Keep in dry and cool conditions
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use
Other Features
Fluorescence: NA
Applications
1) Efficient CO2 capture and conversion, suitable for CO2 adsorption and transformation applications.
2) Catalyzing the cycloaddition of CO2 with epoxides to produce cyclic carbonates.
2) Catalyzing the cycloaddition of CO2 with epoxides to produce cyclic carbonates.
Characterizations
References
1) Yuliang Zhao, Hongliang Huang, Hejin Zhu, Chongli Zhong; Microporous and Mesoporous Materials, 2022, 329, 111526, DOI: 10.1016/j.micromeso.2021.111526, Design and synthesis of novel pyridine-rich cationic covalent triazine framework for CO2 capture and conversion