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4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
CAS:136809-42-2 M.F.:C32H16N2 M.W.:428.48284
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Product Name:4,​4'-​(9,​10-​Anthracenediyldi-​2,​1-​ethynediyl)​bis[benzonitrile]
Synonymous:
CAS:136809-42-2
Basic Info
M.F. C32H16N2 M.W. 428.48284
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Akiyama, S.; Nakatsuji, S.; Nomura, K.; Matsuda, K.; Nakashima, K.; J. Chem. Soc., Chem. Commun. 1991, (14), 948-950, DOI:10.1039/C39910000948 ; Direct C≡C triple bond formation from the C=C double bond with potassium tert-​butoxide in dimethylformamide containing trace amounts of oxygen
2) Nguyen, P.; Todd, S.; Van den Biggelaar, D.; Taylor, N.; Marder, T.; Wittmann, F.; Friend, R.; Synlett 1994, (4), 299-301, DOI: 10.1055/s-1994-22837 ; Facile route to highly fluorescent 9,​10-​bis(p-​R-​phenylethynyl)​anthracene chromophores via palladium-​copper catalyzed cross-​coupling
3) Fudickar, W.; Linker, T.; Chem.- Eur. J. 2011), 17(49), 13661-13664, DOI: 10.1002/chem.201102230 ; Reversible Photooxygenation of Alkynylanthracenes: Chemical Generation of Singlet Oxygen under Very Mild Conditions
4) Fudickar, W.; Linker, T.; J. Am. Chem. Soc. 2012, 134(36), 15071-15082, DOI: 10.1021/ja306056x ; Why Triple Bonds Protect Acenes from Oxidation and Decomposition
4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile

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