CAS 136538-84-6|DPBH|CHEMSOON-MOF/COFmaterial professional supplier

Product Name：1,3-Di(2-pyridyl)benzene
Synonymous：DPBH;2,2'-(1,3-Phenylene)bis[pyridine]; 1,3-Bis(2-pyridinyl)benzene; 1,3-Bis(2-pyridyl)benzene;
CAS：136538-84-6

Basic Info

M.F.	C16H12N2		M.W.	232.27988
Appearance

Properties

1) It is soluble in DMF and DMSO
2) Sealed at room temperature

Appications

1) It could be used as monomer linker for MOF synthesis:Ru(tterpy)(dpb) [r1]

Characterization

HNMR

FTIR

HPLC

Reference

1) Beley, Marc; Collin, Jean Paul; Louis, Remy; Metz, Bernard; Sauvage, Jean Pierre; J. Am. Chem. Soc. 1991, 113(22), 8521-8522, DOI: 10.1021/ja00022a049 ; 3,3',5,5'-Tetrapyridylbiphenyl, a bis-cyclometalating bridging ligand with a high coupling ability in ruthenium(III), ruthenium(II) mixed valence systems

2) Cardenas, Diego J.; Echavarren, Antonio M.; Ramirez de Arellano, M. Carmen; Organometallics 1999, 18(17), 3337-3341, DOI: 10.1021/om990125g ; Divergent Behavior of Palladium(II) and Platinum(II) in the Metalation of 1,3-Di(2-pyridyl)benzene

3) Williams, J. A. Gareth; Beeby, Andrew; Davies, E. Stephen; Weinstein, Julia A.; Wilson, Claire; Inorg. Chem. 2003, 42(26), 8609-8611, DOI: 10.1021/ic035083+ ; An Alternative Route to Highly Luminescent Platinum(II) Complexes: Cyclometalation with N-C-N-Coordinating Dipyridylbenzene Ligands

4) Soro, Barbara; Stoccoro, Sergio; Minghetti, Giovanni; Zucca, Antonio; Cinellu, Maria Agostina; Gladiali, Serafino; Manassero, Mario; Sansoni, Mirella; Organometallics 2005, 24(1), 53-61, DOI: 10.1021/om040102o ; Synthesis of the First C-2 Cyclopalladated Derivatives of 1,3-Bis(2-pyridyl)benzene. Crystal Structures of [Hg(N-C-N)Cl], [Pd(N-C-N)Cl], and [Pd2(N-C-N)2(μ-OAc)]2[Hg2Cl6]. Catalytic Activity in the Heck Reaction

5) Kletsch, Lukas; Hoerner, Gerald; Klein, Axel; Organometallics 2020, 39(15), 2820-2829, DOI: 10.1021/acs.organomet.0c00355 ; Cyclometalated Ni(II) Complexes [Ni(N[symbol omitted]C[symbol omitted]N)X] of the Tridentate 2,6-di(2-pyridyl)phenide Ligand