Product Name:3,3',3'',3'''-Methanetetrayltetrakis[6-hydroxybenzaldehyde]Synonymous:TFHPM;tetrakis(salicylaldehyde)methane CAS:1352523-65-9
Basic Info
M.F. |
C29H20O8 |
M.W. |
496.4643 |
Appearance |
 |
Properties
1) It is soluble in DCM,DMF,DMSO,etc.
2) Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:3D-Salphen-COFs JUC-509 [r4]; TzTz-POP-5 [r3]
Characterization
Reference
1) Mastalerz, Michael; Oppel, Iris M.; European Journal of Organic Chemistry 2011, 2011(30), 5971-5980, S5971/1-S5971/25, DOI: 10.1002/ejoc.201100745 ; Synthesis of Tetrahedral Shape-Persistent Tetranuclear Metal-salphens
2) Mastalerz, Michael; Hauswald, Hans-Jochen S.; Stoll, Raphael; Chemical Communications 2012, 48(1), 130-132, DOI: 10.1039/C1CC14805B ; Metal-assisted salphen organic frameworks (MaSOFs) with high surface areas and narrow pore-size distribution
3) Biswal, Bishnu P.; Becker, Daniel; Chandrasekhar, Naisa; Seenath, Jensheer Shamsudeen; Paasch, Silvia; Machill, Susanne; Hennersdorf, Felix; Brunner, Eike; Weigand, Jan J.; Berger, Reinhard; Feng, Xinliang; Chemistry - A European Journal 2018, 24(42), 10868-10875, DOI: 10.1002/chem.201802631 ; Exploration of Thiazolo[5,4-d]thiazole Linkages in Conjugated Porous Organic Polymers for Chemoselective Molecular Sieving
4) Yan, Shichen; Guan, Xinyu; Li, Hui; Li, Daohao; Xue, Ming; Yan, Yushan; Valtchev, Valentin; Qiu, Shilun; Fang, Qianrong; Journal of the American Chemical Society 2019, 141(7), 2920-2924, DOI: 10.1021/jacs.9b00485 ; Three-dimensional Salphen-based Covalent-Organic Frameworks as Catalytic Antioxidants