Iron, diaquatris[μ-([1,1′-biphenyl]-4,4′-dicarboxylato(2-)-κO4:κO′4)]fluoro-μ3-oxotri-
Iron, diaquatris[μ-([1,1′-biphenyl]-4,4′-dicarboxylato(2-)-κO4:κO′4)]fluoro-μ3-oxotri-
CAS:1341135-53-2
M.F.:C42H28FFe3O15
M.W.:959.20
Pricing
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Product: MIL-88D
Synonyms:
CAS：1341135-53-2
Basic Information
| Unit MF. | C42H28FFe3O15 | Unit MW. | 959.20 | ||
| Coordination Metal | Fe | Linker |
4,4'-biphenyl dicarboxylate (C12H8(CO2)2) |
||
| Pore Size | ~6 Å | Pore Volume | 0.2 cm3/g | ||
| Surface Area | 208 m2/g | ||||
| Analog Structure | |||||
Product Property
| Appearance | ||||
| Particle Size | Micron-sized | |||
Stability
1) Stable in dry conditions, but may partially hydrolyze in humid air.
2) Thermal decomposition temperature is around 200°C.
2) Thermal decomposition temperature is around 200°C.
Preservation
1) Keep in dry and cool conditions.
2) Activate by heating in a vacuum oven at room temperature for 3 hours before use.
Other Features
1) Flexibility: MIL-88D exhibits significant structural flexibility, with large changes in unit cell volume upon solvent adsorption.
2) Adsorption: High affinity for polar solvents, leading to large pore opening.
2) Adsorption: High affinity for polar solvents, leading to large pore opening.
Applications
1) Gas storage and separation, especially for polar gases.
2) Catalyst support in organic reactions.
3) Drug delivery systems.
2) Catalyst support in organic reactions.
3) Drug delivery systems.
Characterizations
References
1) Patricia Horcajada, Fabrice Salles, Stefan Wuttke, Thomas Devic, Daniela Heurtaux, Guillaume Maurin, Alexandre Vimont, Marco Daturi, Olivier David, Emmanuel Magnier, Norbert Stock, Yaroslav Filinchuk, Dmitry Popov, Christian Riekel, Gérard Férey, Christian Serre; Journal of the American Chemical Society (2011), 133, 17839–17847, DOI: 10.1021/ja206936e; How Linker’s Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88.