Iron, μ3-oxotris[μ-[2,3,5,6-tetrafluoro-1,4-benzenedicarboxylato(2-)-κO1:κO′1]]tri-
Iron, μ3-oxotris[μ-[2,3,5,6-tetrafluoro-1,4-benzenedicarboxylato(2-)-κO1:κO′1]]tri-
CAS:1341134-31-3
M.F.:C24F12Fe3O13
M.W.:891.77
Pricing
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Product: F4-MIL-88B
Synonyms: Iron, μ3-oxotris[μ-[2,3,5,6-tetrafluoro-1,4-benzenedicarboxylato(2-)-κO1:κO′1]]tri-
CAS: 1341134-31-3
Basic Information
| Unit MF. | C24F12Fe3O13 | Unit MW. | 891.77 | ||
| Coordination Metal | Fe | Linkers |
Terephthalic acid (4-fluorinated) (CAS: 353-67-1) |
||
| Pore Size | ~3.8 Å | Pore Volume | NA | ||
| Surface Area | 32 m²/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | Brown powders | |||
| Particle Size | NA | |||
Stability
1) Stable in ethanol and other solvents
2) Thermal decomposition temperature around 200°C
2) Thermal decomposition temperature around 200°C
Preservation
1) Keep in dry and cool conditions
2) Suggest vacuum drying at room temperature for 3 hours before use
Other Features
Fluorescence: NA
Applications
1) Efficient in adsorption of CO2, N2 and other gases
2) Useful for gas storage (e.g., H2, CH4)
3) Catalytic reaction carrier
2) Useful for gas storage (e.g., H2, CH4)
3) Catalytic reaction carrier
Characterizations
References
1) Horcajada, Patricia; Salles, Fabrice; Wuttke, Stefan; Devic, Thomas; Heurtaux, Daniela; Maurin, Guillaume; Vimont, Alexandre; Daturi, Marco; David, Olivier; Magnier, Emmanuel; Stock, Norbert; Filinchuk, Yaroslav; Popov, Dmitry; Riekel, Christian; Férey, Gérard; Serre, Christian; J. Am. Chem. Soc., 2011, 133(48), 17839-17847, DOI: 10.1021/ja206936e, How Linker’s Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88