Product: UIO-66-SO3H
Synonyms: NA
CAS:1334722-07-4
Basic Information
Unit MF. |
C48H3O50S6Zr6-6.H+ |
Unit MW. |
2120.25 |
Coordination Metal |
Zr |
Linkers |
2-sulfoterephthalic acid (CAS: 4991-22-4) |
Pore Size |
0.8nm; 1.1nm |
Pore volume |
NA |
Surface Area |
BET Specific surface 380 m2/g, |
Analog Structure |
 |
Product Property
Appearance |
White Powder |
|
Particle Size |
NA |
Stability
1) UIO-66-SO3H is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2)High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Sulfo-group could be used as acidic catalyst and cation membrane
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850–13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) S. J. Garibaya, S. M. Cohen, Chem. Commun., 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology