UIO-66-COOH
UIO-66-COOH
CAS:1334722-04-1
M.F.:C54H22O44Zr6.H6
M.W.:1928.12
Pricing
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Product: UIO-66-COOH
Synonyms: NA
CAS：1334722-04-1
Basic Information
| Unit MF. | C54H18O44Zr6-6.H+ | Unit MW. | 1918.90 | ||
| Coordination Metal | Zr | Linkers | Trimellitic acid (CAS: 528-44-9) | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | |||
| Surface Area | BET Specific surface 600-700 m2/g, | ||||
| Analog Structure | |||||
Product Property
| Appearance | Off-White Powder | |||
| Particle Size | 200-800nm | |||
Stability
1) UIO-66-COOH is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 350 ° C
2）High thermal stability, thermal decomposition temperature above 350 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) UIO-66-COOH has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
2) UIO-66-COOH has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54, 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs
3) Y. Khabzina, J. Dhainaut, M. Ahlhelm, H.-J. Richter, H. Reinsch, N. Stock, D. Farrusseng, Ind. Eng. Chem. Res. 2018, 57, 24, 8200-8208, DOI: 10.1021/acs.iecr.8b00808 ; Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters