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MIL-101(Cr)-SO3H
MIL-101(Cr)-SO3H
CAS:1331961-41-1 M.F.:C24H15Cr3O25S3.H2 M.W.:957.56
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Product: MIL-101(Cr)-SO3H
Synonyms: NA
CAS:1331961-41-1

Basic Information
Unit MF. C24HO25S3Cr3-2.H2O.H+ Unit MW. 700.2355
Coordination  Metal Cr Linkers Terephthalic acid (CAS:100-21-0)
Aperture

Aperture:1.2-1.6nm;  Pore Size: 2.9-3.4nm

Pore volume ~2.0 cm3/g
Surface Area BET Specific surface 1800-2000 m2/g,
Analog Structure  
Product Property
Appearance Grey Green Powder  
Particle Size 300-1um irregular
Stability
1) MIL-101(Cr)-SO3H is stable in air and acqeous solutions (PH 1-12)
2)Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition 
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) The -SO3H group could be further modified; it could be used as ion-probe or composed in membrane materials
Characterizations
XRD
BET
SEM
 SEM-MIL-101(Cr)-SO3H
FTIR
FTIR-MIL-101(Cr)-SO3H
References
1) G. Akiyama, R. Matsuda, H. Sato, M. Takata, S. Kitagawa, Adv. Mater. 2011, 23, 3294–3297, DOI: 10.1002/adma.201101356 ; Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups
MIL-101(Cr)-SO3H
MIL-101(Cr)-SO3H

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