Tris[μ-[3,5-dimethyl-1H-pyrazole-4-carboxylato(2-)-κO4:κO′4]]-μ4-oxotetrazinc
Tris[μ-[3,5-dimethyl-1H-pyrazole-4-carboxylato(2-)-κO4:κO′4]]-μ4-oxotetrazinc
CAS:1318157-58-2
M.F.:C18H18N6O7Zn4
M.W.:691.95
Pricing
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Material Name: Zn-bzc-2CH3 MOF
Synonyms: NA
CAS: 1318157-58-2
Structural Information
| Unit Formula | C18H18N6O7Zn4 | Molecular Weight | 691.95 | ||
| Coordination Metal | Zn | Linker |
3,5-dimethylpyrazole-4-carboxylic acid (bzc-2CH3) |
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| Pore Size | 4.13 Å | Pore Volume | |||
| Surface Area | 378.2 m²/g | ||||
| Simulated Structure | |||||
Product Appearance
| Appearance | White crystalline powder | |||
| Particle Size | ||||
Stability
1) Zn-bzc-2CH3 MOF is stable in water and air for extended periods (72 hours in water and 30 days in air).
2) Thermal decomposition temperature is not explicitly mentioned, but the material shows excellent stability in ambient conditions.
2) Thermal decomposition temperature is not explicitly mentioned, but the material shows excellent stability in ambient conditions.
Preservation and Activation
1) Store in a dry and cool place.
2) Activate by heating at 140°C under vacuum for 4 hours before use.
Other Features
High affinity for n-C4H10 and selective exclusion of iso-C4H10. Excellent water stability and humidity resistance.
Applications
1) Efficient separation of n-C4H10/iso-C4H10 under humid conditions.
2) Ideal molecular-sieving effect for industrial gas separation.
2) Ideal molecular-sieving effect for industrial gas separation.
Characterizations
References
1）Wang, Lu; Xue, Wenjuan; Zhu, Hejin; Guo, Xiangyu; Huang, Hongliang; Zhong, Chongli; Angew. Chem. Int. Ed. 2023, 62, e202218596; DOI: 10.1002/anie.202218596; Stepwise Engineering the Pore Aperture of a Cage-like MOF for the Efficient Separation of Isomeric C4 Paraffins under Humid Conditions