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COF-42
COF-42
CAS:1314877-67-2 M.F.:C12H18N4O4.C9H6O3 M.W.:444.44
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Product: COF-42
Synonyms: 4-Benzenedicarboxylic acid, 2,5-diethoxy-, 1,4-dihydrazide, polymer with 1,3,5-benzenetricarboxaldehyde
CAS:1314877-67-2

Basic Information
Unit MF. C12H18N4O4.C9H6O3 Unit MW. 444.43786
Linkers  2,5-Diethoxy-terephthalohydrazide(CAS:1136292-71-1);

1,3,5-benzenetricarboxaldehyde (3163-76-6)

Aperture 2.8 nm Pore volume 0.31 cm3/g
Surface Area BET比表面710m2/g
Analog Structure   
Product Property
Appearance Pale-yellow powder  
Particle Size  /
Stability
1) Thermally decomposition temperature at about 280 ° C
Preservation
1) Dry and sealed under normal temperature or low temperature conditions 
Other Features
Fluorescence:NA
Applications
1) For gas and pollutant adsorption
2) Good pores can be used to load other catalysts
Characterizations
XRD
XRD-COF-42
SEM
BET
BET-COF-42
FTIR
References
1) F. J. Uribe-Romo, C. J. Doonan, H. Furukawa, K. Oisaki, O. M. Yaghi, J. Am. Chem. Soc. 2011, 133, 11478, DOI: 10.1021/ja204728y ; Crystalline Covalent Organic Frameworks with Hydrazone Linkages
2) S.Y. Ding, X. Cui, J. Feng, G. Lu, W. Wang, Chem. Commun., 2017,53, 11956-11959, DOI: 10.1039/C7CC05779B ; Facile synthesis of –C[double bond, length as m-dash]N– linked covalent organic frameworks under ambient conditions
COF-42
COF-42

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