Product: TPP-NTDA
Synonyms: 1,3,5-tris(4-aminophenyl)benzene-naphthalene tetracarboxylic dianhydride polymer
CAS: 1312707-44-0
Basic Information
Unit MF. |
C24H21N3.C14H4O6 |
Unit MW. |
619.6216 |
Coordination Metal |
None |
Linkers |
1,3,5-tris(4-aminophenyl)benzene (TPP)
Naphthalene-1,4,5,8-tetracarboxylic dianhydride (NTDA)
|
Pore Size |
~6-10 Å |
Pore Volume |
0.40 cm³/g |
Surface Area |
570 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
Brown solid, irregular block-like |
|
Particle Size |
Irregular bulk particles |
Stability
1) Insoluble in common organic solvents, showing good chemical stability.
2) Thermal decomposition temperature > 530°C.
Preservation
1) Keep in dry and cool conditions.
2) No special activation required; can be vacuum-dried at 150°C if needed.
Other Features
NA
Applications
1) Microporous structure suitable for gas adsorption and separation.
2) High thermal stability makes it suitable for high-temperature applications.
3) Ideal for studying the relationship between polymer network topology and performance.
Characterizations
References
1) Wang, Zhonggang; Zhang, Bufeng; Yu, Hao; Li, Guiyang; Bao, Yajie; Soft Matter (2011), 7(18), 5723-5730, DOI: 10.1039/c1sm05315a, Synthetic control of network topology and pore structure in microporous polyimides based on triangular triphenylbenzene and triphenylamine units;
2)Sandip Biswas, Atin Pramanik, Anupam Dey, Shreyasi Chattopadhyay,Tymofii S. Pieshkov, Sohini Bhattacharyya, Pulickel M. Ajayan,* and Tapas Kumar Maji*; Small 2024, 20, 2406173; DOI: 10.1002/smll.202406173; 2D Covalent Organic Framework Covalently Anchored with Carbon Nanotube as High-Performance Cathodes for Lithium and Sodium-Ion Batteries