CAS 1265529-85-8|H2BME-bdc|H2BDC-2OEtOMe|CHEMSOON-MOF/COF material professional supplier

Product Name：2,5-Bis(2-methoxyethoxy)terephthalic acid
Synonymous：H2BME-bdc; H2BDC-2OEtOMe;2,5-Bis(2-methoxyethoxy)-1,4-benzenedicarboxylic acid
CAS：1265529-85-8

Basic Info

M.F.	C14H18O8		M.W.	314.28792
Appearance

Properties

1) It is soluble in DMF and DMSO
2) Sealed at room temperature

Appications

1) It could be used as monomer linker for MOF synthesis：M2(BME-bdc)2(dabco) (M2+ = Zn2+, Co2+, Ni2+, Cu2+) [r1]; UIO-66-2OEtOMe [r4]

Characterization

HNMR

FTIR

HPLC

Reference

1) Henke, Sebastian; Schmid, Rochus; Grunwaldt, Jan-Dierk; Fischer, Roland A.; Chem.-Eur. J. 2010, 16(48), 14296-14306, DOI: 10.1002/chem.201002341 ; Flexibility and Sorption Selectivity in Rigid Metal-Organic Frameworks: The Impact of Ether-Functionalised Linkers

2) Henke, Sebastian; Fischer, Roland A.; J. Am. Chem. Soc. 2011, 133(7), 2064-2067, DOI: 10.1021/ja109317e ; Gated Channels in a Honeycomb-like Zinc-Dicarboxylate-Bipyridine Framework with Flexible Alkyl Ether Side Chains

3) Schneemann, Andreas; Vervoorts, Pia; Hante, Inke; Tu, Min; Wannapaiboon, Suttipong; Sternemann, Christian; Paulus, Michael; Wieland, D. C. Florian; Henke, Sebastian; Fischer, Roland A.; Chem. Mater 2018, 30(5), 1667-1676, DOI: 10.1021/acs.chemmater.7b05052 ; Different Breathing Mechanisms in Flexible Pillared-Layered Metal-Organic Frameworks: Impact of the Metal Center

4) Fast, Caleb D.; Woods, Jason; Lentchner, Jared; Makal, Trevor A.; Dalton Trans. 2019, 48(39), 14696-14704,DOI: 10.1039/c9dt03004b ; Stabilizing defects in metal-organic frameworks: pendant Lewis basic sites as capping agents in UiO-66-type MOFs toward highly stable and defective porous materials