MOF-253
MOF-253
CAS:1251862-76-6
M.F.:C12H7AlN2O5
M.W.:286.18
Pricing
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Product: MOF-253(Al)
Synonyms: MIL-53(Al)-DCBPy; Al(OH)(dcbpy)
CAS：1251862-76-6
Basic Information
| Unit MF. | C12H6N2O5Al | Unit MW. | 285.16794 | ||
| Coordination Metal | Al | Linkers |
2,2′-bipyridine-5,5′-dicarboxylic acid (CAS: 1802-30-8) |
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| Aperture | pore channels 1.0nm*1.5nm | Pore volume | 0.7 cm3/g | ||
| Surface Area | BET Specific surface 1100 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | White Powder |  |
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| Particle Size | irregular flakes or rod nanoparticles | |||
Stability
1) MOF-253(Al) is could be kept stable for several weeks in dry air. It is not in wet air or in aqueous solutions
2) High thermal stability, thermal decomposition temperature above 300 ° C
2) High thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas and pollutant adsorption
2) With open 2,2′-bipyridine (bpy) coordination sites, MOF-253 could be further coordinated with metals(e.g. Pt, Pd, Cu) to form active photocatalyst and lewis acid catalyst for organic reactions
2) With open 2,2′-bipyridine (bpy) coordination sites, MOF-253 could be further coordinated with metals(e.g. Pt, Pd, Cu) to form active photocatalyst and lewis acid catalyst for organic reactions
Characterizations
References
1) Bloch, E. D.; Britt, D.; Lee, C.; Doonan, C. J.; Uribe-Romo, F. J.; Furukawa, H.; Long, J. R.; Yaghi, O. M.; J.
Am. Chem. Soc. 2010, 132, 14382-14384, DOI: 10.1021/ja106935d ; Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
2) Deng, X.; Qin, Y.; Hao, M.; Li, Z.; Inorg. Chem. 2019, 58, 24, 16574-16580, DOI: 10.1021/acs.inorgchem.9b02593 ; MOF-253-Supported Ru Complex for Photocatalytic CO2 Reduction by Coupling with Semidehydrogenation of 1,2,3,4-Tetrahydroisoquinoline (THIQ)