Product: TAPA-PDA-COF
Synonyms:
CAS:1244037-88-4
Basic Information
Unit MF. |
(C18H18N4.C8H6O2)x |
Unit MW. |
424.50 |
Linkers |
1) Tris(4-aminophenyl)amine(CAS: 5981-09-9)
2) Terephthalaldehyde (CAS:623-27-8)
|
Aperture |
~1.3 nm 和 2.1 nm |
Pore volume |
0.52 cm³/g |
Surface Area |
>648 m²/g |
Analog Structure |
|
Product Property
Appearance |
powder |
|
Particle Size |
/ |
Stability
1) It is stable in N2 environment, with a maximum stable temperature of up to 400 ° C
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) It is recommended to activate for 12 hours at 60 degree in vacuum before gas adsorption test
Other Features
Fluorescence:NA
Applications
1) It can be used for gas storage and separation;
2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Gaurav Kumar Silori, Szu-Chia Chien, Li-Chiang Lin, and Kuo-Chuan Ho; Angew. Chem. Int. Ed. 2024, e202416046; DOI:10.1002/anie.202416046; Four-State Electrochromism in Tris(4-aminophenyl)amineterephthalaldehyde-based Covalent Organic Framework;
【文献解读】
2) Tran, Ly D.; Presley, Kayla F.; Streit, Jason K.; et al. Chem. Mater. 2022, 34, 529−536. DOI: 10.1021/acs.chemmater.1c02565; Divergent Properties in Structural Isomers of Triphenylamine-Based Covalent Organic Frameworks.