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CAS:1239608-21-9 M.F.:C20H10O8 M.W.:378.2886
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Product Name:1,​1'-​butadiynebenzene-​3,​3',​5,​5'-​tetracarboxylic acid
Synonymous:H4BDDC ; H4BBTC ; DPBDTC;5,​5'-​(1,​3-​Butadiyne-​1,​4-​diyl)​bis[1,​3-​benzenedicarboxylic acid] ; 5,​5'-​(butadiyne-​1,​4-​diyl)​diisophthalic acid ; 1,4-diphenyl-1,3-butadiyne-3,3′′,5,5′′-tetracarboxylic acid
CAS:1239608-21-9
Basic Info
M.F. C20H10O8 M.W. 378.2886
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Cu2(BDDC)​(H2O)​2]​·DMF·3H2O [r1]; [Eu2(BBTC)​1.5(CH3OH)​2(H2O)​2]​ [r2]; [Ln2(BBTC)​1.5(DMF)​4]​ [r4]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Zheng, Bing; Liang, Zhiqiang; Li, Guanghua; Huo, Qisheng; Liu, Yunling; Cryst. Growth & Des. 2010, 10(8), 3405-3409, DOI: 10.1021/cg100046j ; Synthesis, Structure, and Gas Sorption Studies of a Three-​Dimensional Metal-​Organic Framework with NbO Topology
2) Wang, Li-Feng; Kang, Ling-Chen; Zhang, Wen-Wei; Wang, Fang-Ming; Ren, Xiao-Ming; Meng, Qing-Jin; Dalton Trans. 2011, 40(37), 9490-9497, DOI: 10.1039/c1dt10693g ; New europium coordination polymers with efficient energy transfer from conjugated tetracarboxylate ligands to Eu3+ ion: syntheses, structures, luminescence and magnetic properties
3) Stannard, Andrew; Russell, James C.; Blunt, Matthew O.; Salesiotis, Christos; Gimenez-Lopez, Maria del Carmen; Taleb, Nassiba; Schroeder, Martin; Champness, Neil R.; Garrahan, Juan P.; Beton, Peter H.; Nature Chem. 2012, 4(2), 112-117, DOI: 10.1038/nchem.1199 ; Broken symmetry and the variation of critical properties in the phase behaviour of supramolecular rhombus tilings
4) Rong, Jiewei; Zhang, Wenwei; Bai, Junfeng; RSC Adv. 2016, 6(105), 103714-103723, DOI: 10.1039/C6RA22001K ; Synthesis and structure of color tunable and white-​light emitting lanthanide metal-​organic framework materials constructed from conjugated 1,​1'-​butadiynebenzene-​3,​3',​5,​5'-​tetracarboxylate ligand

5) Shao, Kai; Pei, Jiyan; Wang, Jia-Xin; Yang, Yu; Cui, Yuanjing; Zhou, Wei; Yildirim, Taner; Li, Bin; Chen, Banglin; Qian, Guodong; Chem. Commun. 2019, 55(76), 11402-11405, DOI: 10.1039/c9cc06239d ; Tailoring the pore geometry and chemistry in microporous metal-​organic frameworks for high methane storage working capacity


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