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4',4'',4''',4''''-methanetetrayltetrabiphenyl-4-carboxylic acid
4',4'',4''',4''''-methanetetrayltetrabiphenyl-4-carboxylic acid
CAS:1208241-38-6 M.F.:C53H36O8 M.W.:800.84814
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Product Name:4',4'',4''',4''''-methanetetrayltetrabiphenyl-4-carboxylic acid
Synonymous:H4MTBC
CAS:1208241-38-6
Basic Info
M.F.  C53H36O8 M.W.  800.84814
Appearance
Properties
1) 1208241-38-6  is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis: PCN-521(Zr) PCN-523(Hf) [r2]; Zr-MTBC [r3]; MV-OCN-521 [r4]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Ma, L.; Jin, A.; Xie, Z.; Lin, W.; Angew. Chem., Int. Ed. 2009, 48(52), 9905-9908, DOI:10.1002/anie.200904983 ; Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4‐Connected Metal–Organic Frameworks   
2) M. Zhang, Y. P. Chen, M. Bosch, T. Gentle, K. Wang, D. Feng, H. C. Zhou, Angew. Chem., Int. Ed. 2014, 53(3), 815-818, DOI:10.1002/anie.201307340 ; Symmetry‐Guided Synthesis of Highly Porous Metal–Organic Frameworks with Fluorite Topology
3) Ji, P.; Manna, K.; Lin, Z.; Urban, A.; Greene, F.; Lan, G.; Lin, W.; J. Am. Chem. Soc. 2016, 138(37), 12234-12242, DOI:10.1021/jacs.6b06759
4) Wang, Y.; Liu, Q.; Zhang, Q.; Peng, B.; Deng, H.; Angew. Chem., Int. Ed. 2018, 57(24), 7120-7125, DOI: 10.1002/ange.201307340
HNMR-1208241-38-6-CS013128.pdf Download
1208241-38-6-CS014268.pdf Download
1208241-38-6-CS014314.pdf Download
4',4'',4''',4''''-methanetetrayltetrabiphenyl-4-carboxylic acid
4',4'',4''',4''''-methanetetrayltetrabiphenyl-4-carboxylic acid

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