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4-[[3,5-bis[(4-carboxyphenyl)carbamoyl]benzoyl]amino]benzoic acid
4-[[3,5-bis[(4-carboxyphenyl)carbamoyl]benzoyl]amino]benzoic acid
CAS:120360-51-2 M.F.:C30H21N3O9 M.W.:567.50244
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Product Name:N,N′,N′′-bis-(4-carboxylate)trimesicamide
Synonymous:H3bcta ; H3btcit; H3BTCB;4,​4',​4''-​[1,​3,​5-​Benzenetriyltris(car​bonylimino)​]​trisbenzoic acid
CAS:120360-51-2
Basic Info
M.F. C30H21N3O9 M.W. 567.50244
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
It could be used as monomer linker for MOF synthesisDUT-32 [r4]; Y-PCP, La-PCP [r4]; tp-PMBB-1-asc-3 [r5]; 3D-ROD-1 [r6]
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) Aharoni, S. M.; Edwards, S. F.; Macromolecules (1989), 22(8), 3361-3374, DOI: 10.1021/ma00198a030 ; Gels of rigid polyamide networks
2) Bernet, Andreas; Albuquerque, Rodrigo Q.; Behr, Marina; Hoffmann, Sebastian T.; Schmidt, Hans-Werner; Soft Matter 2012, 8(1), 66-69, DOI: 10.1039/C1SM06789C ; Formation of a supramolecular chromophore: a spectroscopic and theoretical study
3) Duan, Jingui; Higuchi, Masakazu; Foo, Maw Lin; Horike, Satoshi; Rao, Koya Prabhakara; Kitagawa, Susumu; Inorg. Chem. 2013, 52(14), 8244-8249, DOI: 10.1021/ic401157n ; A Family of Rare Earth Porous Coordination Polymers with Different Flexibility for CO2​/C2H4 and CO2​/C2H6 Separation
4) Gruenker, Ronny; Bon, Volodymyr; Mueller, Philipp; Stoeck, Ulrich; Krause, Simon; Mueller, Uwe; Senkovska, Irena; Kaskel, Stefan; Chem. Commun., 2014,50, 3450-3452, DOI: 10.1039/C4CC00113C ; A new metal–organic framework with ultra-high surface area

5) Schoedel, Alexander; Cairns, Amy J.; Belmabkhout, Youssef; Wojtas, Lukasz; Mohamed, Mona; Zhang, Zhenjie; Proserpio, Davide M.; Eddaoudi, Mohamed; Zaworotko, Michael J.; Angew. Chem., Int. Ed. 2013, 52(10), 2902-2905, DOI: 10.1002/anie.201206042 ; The asc Trinodal Platform: Two-​Step Assembly of Triangular, Tetrahedral, and Trigonal-​Prismatic Molecular Building Blocks6) Zhang, Yu-Feng; Zhang, Zong-Hui; Ritter, Logan; Fang, Han; Wang, Qian; Space, Brian; Zhang, Yue-Biao; Xue, Dong-Xu; Bai, Junfeng; Journal of the American Chemical Society 2021, 143(31), 12202-12211, DOI: 10.1021/jacs.1c04946 ; New Reticular Chemistry of the Rod Secondary Building Unit: Synthesis, Structure, and Natural Gas Storage of a Series of Three-​Way Rod Amide-​Functionalized Metal-​Organic Frameworks

120360-51-2-CS017657.pdf Download
120360-51-2-CS017657-MS.pdf Download
4-[[3,5-bis[(4-carboxyphenyl)carbamoyl]benzoyl]amino]benzoic acid
4-[[3,5-bis[(4-carboxyphenyl)carbamoyl]benzoyl]amino]benzoic acid

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