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4,4'-((1E,1'E)-(2,5-dimethoxy-1,4-phenylene)bis(ethene-2,1-diyl))dibenzoic acid
4,4'-((1E,1'E)-(2,5-dimethoxy-1,4-phenylene)bis(ethene-2,1-diyl))dibenzoic acid
CAS:1202253-60-8 M.F.:C26H22O6 M.W.:430.44928
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Product Name:4,​4'-​[(2,​5-​Dimethoxy-​1,​4-​phenylene)​di-​(1E)​-​2,​1-​ethenediyl]​bis[benzoicacid]
Synonymous:H2-PVDC;(E,​E)​-​2,​5-​dimethoxy-​1,​4-​bis[2-​(4-​carboxylatestyryl)​]​benzene
CAS:1202253-60-8
Basic Info
M.F. C26H22O6 M.W. 430.44928
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:近红外MOF材料: Yb-PVDC-1 [r1]; Yb-PVDC-2 [r2]; Yb-PVDC-3 [r3]
Characterization
HNMR
MS
CNMR
HPLC
NA
Reference
1) White, Kiley A.; Chengelis, Demetra A.; Zeller, Matthias; Geib, Steven J.; Szakos, Jessica; Petoud, Stephane; Rosi, Nathaniel L.; Chem. Commun. 2009, (30), 4506-4508, DOI: 10.1039/b909658b ; Near-​infrared emitting ytterbium metal-​organic frameworks with tunable excitation properties
2) White, Kiley A.; Chengelis, Demetra A.; Gogick, Kristy A.; Stehman, Jack; Rosi, Nathaniel L.; Petoud, Stephane; Journal of the American Chemical Society 2009, 131(50), 18069-18071, DOI:10.1021/ja907885m ; Near-​Infrared Luminescent Lanthanide MOF Barcodes
3) Foucault-Collet, Alexandra; Gogick, Kristy A.; White, Kiley A.; Villette, Sandrine; Pallier, Agnes; Collet, Guillaume; Kieda, Claudine; Li, Tao; Geib, Steven J.; Rosi, Nathaniel L.; Petoud, Stephane; PNAS 2013, 110(43), 17199-17204, DOI: 10.1073/pnas.1305910110 ; Lanthanide near infrared imaging in living cells with Yb3+ nano metal organic frameworks
4) Cardenas, Juan C.; Aguirre-Diaz, Lina M.; Galindo, Johan F.; Ali-Torres, Jorge; Ochoa-Puentes, Cristian; Echeverri, Marcelo; Gomez-Lor, Berta; Monge, M. Angeles; Gutierrez-Puebla, Enrique; Sierra, Cesar A.; Cryst. Growth & Des. 2019, 19(7), 3913-3922, DOI: 10.1021/acs.cgd.9b00328 ; Nature of Color Diversity in Phenylenevinylene-​Based Polymorphs
5) Acelas, Mauricio; Sierra, Cesar A.; J. Photochem. Photobio., A 2021, 405, 112980, DOI: 10.1016/j.jphotochem.2020.112980 ; The oligomer approach: An effective strategy to assess phenylene vinylene systems as organic heterogeneous photocatalysts in the degradation of aqueous indigo carmine dye
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4,4'-((1E,1'E)-(2,5-dimethoxy-1,4-phenylene)bis(ethene-2,1-diyl))dibenzoic acid
4,4'-((1E,1'E)-(2,5-dimethoxy-1,4-phenylene)bis(ethene-2,1-diyl))dibenzoic acid

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