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Benzoic acid, 4,​4'-​[(2,​5-​dimethoxy-​1,​4-​phenylene)​di-​2,​1-​ethynediyl]​bis-
Benzoic acid, 4,​4'-​[(2,​5-​dimethoxy-​1,​4-​phenylene)​di-​2,​1-​ethynediyl]​bis-
CAS:1190438-53-9 M.F.:C26H18O6 M.W.:426.41752
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Product Name:4,​4'-​[(2,​5-​Dimethoxy-​1,​4-​phenylene)​di-​2,​1-​ethynediyl]​bis[benzoic acid]
Synonymous:DMBDA ; PEPEP;
CAS:1190438-53-9
Basic Info
M.F. C26H18O6 M.W. 426.41752
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:MOF-1000 [r1]; PEPEP-PIZOF [r3]; NMOF‐Ome [r4]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Li, Qiaowei; Zhang, Wenyu; Miljanic, Ognjen S.; Sue, Chi-Hau; Zhao, Yan-Li; Liu, Lihua; Knobler, Carolyn B.; Stoddart, J. Fraser; Yaghi, Omar M.; Science 2009, 325(5942), 855-859, DOI: 10.1126/science.1175441 ; Docking in Metal-​Organic Frameworks
2) Zhao, Yan-Li; Liu, Lihua; Zhang, Wenyu; Sue, Chi-Hau; Li, Qiaowei; Miljanic, Ognjen S.; Yaghi, Omar M.; Stoddart, J. Fraser; Chem. Eur. J. 2009, 15(48), 13356-13380, DOI: 10.1002/chem.200902350 ; Rigid-​Strut-​Containing Crown Ethers and [2]​Catenanes for Incorporation into Metal-​Organic Frameworks
3) Lippke, Jann; Brosent, Birte; von Zons, Tobias; Virmani, Erika; Lilienthal, Sebastian; Preusse, Thomas; Huelsmann, Miriam; Schneider, Andreas M.; Wuttke, Stefan; Behrens, Peter; Godt, Adelheid; Inorg. Chem. 2017, 56(2), 748-761, DOI: 10.1021/acs.inorgchem.6b01814 ; Expanding the Group of Porous Interpenetrated Zr-​Organic Frameworks (PIZOFs) with Linkers of Different Lengths
4) Samanta, Debabrata; Roy, Syamantak; Sasmal, Ranjan; Saha, Nilanjana Das; K R, Pradeep; Viswanatha, Ranjani; Agasti, Sarit S.; Maji, Tapas Kumar; Angew. Chem. Int., Ed. 2019, 58(15), 5008-5012, DOI: 10.1002/anie.201900692 ; Solvent adaptive dynamic metal-​organic soft hybrid for imaging and biological delivery
Benzoic acid, 4,​4'-​[(2,​5-​dimethoxy-​1,​4-​phenylene)​di-​2,​1-​ethynediyl]​bis-
Benzoic acid, 4,​4'-​[(2,​5-​dimethoxy-​1,​4-​phenylene)​di-​2,​1-​ethynediyl]​bis-

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