Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-
Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-
CAS:1045720-71-5
M.F.:C24H21O9P3
M.W.:546.33954
Pricing
//
Product Name：1,3,5-Benzene-tri-p-phenylphosphonic acid
Synonymous：H6PPB;P,P'-[5'-(4-Phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis[phosphonic acid]
CAS：1045720-71-5
3) Mah, Roger K.; Lui, Melanie W.; Shimizu, George K. H.; Inorg. Chem. 2013, 52(13), 7311-7313, DOI: 10.1021/ic400274e ; Enhancing Order and Porosity in a Highly Robust Tin(IV) Triphosphonate Framework
4) Pili, Simona; Argent, Stephen P.; Morris, Christopher G.; Rought, Peter; Garcia-Sakai, Victoria; Silverwood, Ian P.; Easun, Timothy L.; Li, Ming; Warren, Mark R.; Murray, Claire A.; Tang, Chiu C.; Yang, Sihai; Schroder, Martin; J. Am. Chem. Soc. 2016, 138(20), 6352-6355, DOI: 10.1021/jacs.6b02194 ; Proton Conduction in a Phosphonate-Based Metal-Organic Framework Mediated by Intrinsic "Free Diffusion inside a Sphere"
Synonymous：H6PPB;P,P'-[5'-(4-Phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis[phosphonic acid]
CAS：1045720-71-5
Basic Info
| M.F. | C24H21O9P3 | M.W. | 546.33954 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:CALF-28 [r3]; MFM-500(M) (M = Ni, Co) [r4]; CAU-25 / [Zn2(H2PPB)(H2O)2] [r5]
Characterization
Reference
1) Beckmann, Jens; Ruettinger, Roman; Schwich, Torsten; Cryst. Growth & Des. 2008, 8(9), 3271-3276, DOI: 10.1021/cg8000569 ; 1,3,5-Benzene-tri-p-phenylphosphonic acid. A new building block in supramolecular chemistry
2) Ouellette, Wayne; Wang, Guangbin; Liu, Hongxue; Yee, Gordon T.; O'Connor, Charles J.; Zubieta, Jon; Inorg. Chem. 2009, 48(3), 953-963, DOI: 10.1021/ic801450m ; The Hydrothermal and Structural Chemistry of Oxovanadium-Arylphosphonate Networks and Frameworks5) Hermer, N.; Reinsch, H.; Mayer, P.; Stock, N.; CrystEngComm 2016, 18(42), 8147-8150, DOI: 10.1039/C6CE01580H ; Synthesis and characterisation of the porous zinc phosphonate [Zn2(H2PPB)(H2O)2]·xH2O