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5-[(3,5-dicarboxyphenyl)methyl]benzene-1,3-dicarboxylic acid
5-[(3,5-dicarboxyphenyl)methyl]benzene-1,3-dicarboxylic acid
CAS:10397-52-1 M.F.:C17H12O8 M.W.:344.27238
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Product Name:5,​5'-​Methylenediisophthal​ic acid
Synonymous:H4mdip; H4MDIA;Isophthalic acid, 5,​5'-​methylenedi- )​; 5,​5'-​Methylenebis[1,​3-​benzenedicarboxylic acid]​;
CAS:10397-52-1
Basic Info
M.F. C17H12O8 M.W. 344.27238
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Zn(H2MDIP)​(4,​4'-​bpy)​0.5] [r1]; [NH2Me2]​[Ln(MDIP)​(H2O)​] [r3]; MIP-177 [r4]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Duan, Xianying; Li, Yizhi; Su, Yang; Zang, Shuangquan; Zhu, Chengjian; Meng, Qingjin; CrystEngComm 2007, 9(9), 758-766, DOI: 10.1039/b618613k ; Syntheses and solid state structures of hybrid d10 metal-​organic frameworks based on methylenediisophthalic acid (H4MDIP)
2) Wang, Xi-Sen; Ma, Shengqian; Forster, Paul M.; Yuan, Daqiang; Eckert, Juergen; Lopez, Joseph J.; Murphy, Brandon J.; Parise, John B.; Zhou, Hong-Cai; Angew. Chem. Int., Ed. 2008, 47(38), 7263-7266, DOI: 10.1002/anie.200802087 ; Enhancing H2 uptake by "close-​packing" alignment of open copper sites in metal-​organic frameworks
3) Su, Shengqun; Chen, Wan; Qin, Chao; Song, Shuyan; Guo, Zhiyong; Li, Guanghua; Song, Xuezhi; Zhu, Min; Wang, Song; Hao, Zhaomin; Zhang, Hongjie; Cryst. Growth & Des. 2012, 12(4), 1808-1815, DOI: 10.1021/cg201283a ; Lanthanide Anionic Metal-​Organic Frameworks Containing Semirigid Tetracarboxylate Ligands: Structure, Photoluminescence, and Magnetism
4) Wang, Sujing; Kitao, Takashi; Guillou, Nathalie; Wahiduzzaman, Mohammad; Martineau-Corcos, Charlotte; Nouar, Farid; Tissot, Antoine; Binet, Laurent; Ramsahye, Naseem; Devautour-Vinot, Sabine; Kitagawa, Susumu; Seki, Shu; Tsutsui, Yusuke; Briois, Valerie; Steunou, Nathalie; Maurin, Guillaume; Uemura, Takashi; Serre, Christian; Nature Commun. 2018, 9(1), 1-9, DOI: 10.1038/s41467-018-04034-w ; A phase transformable ultrastable titanium-carboxylate framework for photoconduction
10397-52-1-CS014885.pdf Download
5-[(3,5-dicarboxyphenyl)methyl]benzene-1,3-dicarboxylic acid
5-[(3,5-dicarboxyphenyl)methyl]benzene-1,3-dicarboxylic acid

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